Statements in which the resource exists as a subject.
PredicateObject
rdf:type
pubmed:issue
Pt 5
pubmed:dateCreated
2011-7-14
pubmed:abstractText
The tetra-nuclear title complex, [Cu(4)(C(7)H(4)O(3))(2)(OH)(2)(C(10)H(8)N(2))(4)](NO(3))(2)·4H(2)O, has a crystallographically imposed centre of symmetry. The Cu(II) atoms display a distorted square-pyramidal coordination geometry and are linked by two ?(2)-phenolate O atoms from the salicylate ligands and two ?(3)-hydroxo groups, forming a Cu(4)O(4) core that adopts a 'stepped-cubane' geometry. In the crystal, the cations are linked by O-H?O hydrogen bonds to the nitrate anions, which are in turn connected via O-H?O inter-actions to centrosymmentric water tetra-mers.
pubmed:commentsCorrections
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
May
pubmed:issn
1600-5368
pubmed:author
pubmed:issnType
Electronic
pubmed:day
1
pubmed:volume
67
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
m520
pubmed:dateRevised
2011-11-11
pubmed:year
2011
pubmed:articleTitle
Tetra-kis(2,2'-bipyrid-ine)di-?(3)-hydroxido-bis(?-2-oxidobenzoato)tetra-copper(II) dinitrate tetra-hydrate.
pubmed:publicationType
Journal Article