Source:http://linkedlifedata.com/resource/pubmed/id/21754263
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Predicate | Object |
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rdf:type | |
pubmed:issue |
Pt 5
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pubmed:dateCreated |
2011-7-14
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pubmed:abstractText |
The tetra-nuclear title complex, [Cu(4)(C(7)H(4)O(3))(2)(OH)(2)(C(10)H(8)N(2))(4)](NO(3))(2)·4H(2)O, has a crystallographically imposed centre of symmetry. The Cu(II) atoms display a distorted square-pyramidal coordination geometry and are linked by two ?(2)-phenolate O atoms from the salicylate ligands and two ?(3)-hydroxo groups, forming a Cu(4)O(4) core that adopts a 'stepped-cubane' geometry. In the crystal, the cations are linked by O-H?O hydrogen bonds to the nitrate anions, which are in turn connected via O-H?O inter-actions to centrosymmentric water tetra-mers.
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pubmed:commentsCorrections | |
pubmed:language |
eng
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pubmed:journal | |
pubmed:status |
PubMed-not-MEDLINE
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pubmed:month |
May
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pubmed:issn |
1600-5368
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pubmed:author | |
pubmed:issnType |
Electronic
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pubmed:day |
1
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pubmed:volume |
67
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
m520
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pubmed:dateRevised |
2011-11-11
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pubmed:year |
2011
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pubmed:articleTitle |
Tetra-kis(2,2'-bipyrid-ine)di-?(3)-hydroxido-bis(?-2-oxidobenzoato)tetra-copper(II) dinitrate tetra-hydrate.
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pubmed:publicationType |
Journal Article
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