Linked Life Data

21709619

Source:http://linkedlifedata.com/resource/pubmed/id/21709619

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
7
pubmed:dateCreated
2011-6-28
pubmed:abstractText
A novel bis-iodurated polyether compound, based on an unprecedented tetra-THF backbone, has been isolated as a trace by-product of the oxidation of squalene with the catalytic system RuO?(cat.)/NaIO?. The double erythro configuration of the central portion of the molecule furnishes the first indirect support of the previously postulated pathway operating in the oxidative pentacyclization of the isoprenoid substrate. A bidirectional double oxidative bis-cyclization is invoked to explain the formation of this compound. The isolated substance was successfully subjected to a double rearrangement-ring expansion to give a novel bis-THF-bis-THP compound.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:issn
1420-3049
pubmed:author
pubmed:issnType
Electronic
pubmed:volume
16
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
5362-73
pubmed:meshHeading
pubmed:year
2011
pubmed:articleTitle
Isolation of a bis-iodurated tetra-THF as a trace product from the oxidation of squalene with RuO? and its double ring expansion to a novel bis-THF-bis-THP compound.
pubmed:affiliation
Dipartimento di Chimica Organica e Biochimica, Università degli Studi di Napoli "Federico II", Via Cynthia 4, 80126 Napoli, Italy. vinpicci@unina.it
pubmed:publicationType
Journal Article