Source:http://linkedlifedata.com/resource/pubmed/id/21699154
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
28
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| pubmed:dateCreated |
2011-7-13
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| pubmed:abstractText |
Single-crystal X-ray diffraction studies have confirmed that Ni(3)S(3)-based molecular bowls prepared in one-pot reactions capture either CH(2)Cl(2) or C(60). The nature of the pendant substituents (naphthalen-2-ylmethyl, benzyl, or ethyl) around the rim of the bowl dictates the formation of a 1:1 (bowl host-C(60) guest) or 2:1 (capsule host-C(60) guest) architecture. In CDCl(3), the trimeric complexes were found to be in equilibrium with dimeric analogues. For the naphthalen-2-ylmethyl-substituted host, NMR spectroscopic titration data confirmed a 1:1 host-C(60) guest complex in 1,2-Cl(2)C(6)D(4) solution.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:month |
Jul
|
| pubmed:issn |
1520-5126
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| pubmed:author | |
| pubmed:issnType |
Electronic
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| pubmed:day |
20
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| pubmed:volume |
133
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
10776-9
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| pubmed:year |
2011
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| pubmed:articleTitle |
Metallohosts with a heart of carbon.
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| pubmed:affiliation |
Department of Chemistry, University of Basel, Spitalstrasse 51, CH-4056 Basel, Switzerland. edwin.constable@unibas.ch
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| pubmed:publicationType |
Journal Article
|