Linked Life Data

21615116

Source:http://linkedlifedata.com/resource/pubmed/id/21615116

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
12
pubmed:dateCreated
2011-6-10
pubmed:abstractText
A straightforward, highly stereoselective protocol toward the synthesis of deuterium-labeled (2R,3S,4S)-?-cyclohexenylserine has been developed. Key steps are a Nozaki-Hiyama-Kishi reaction generating the stereogenic centers and a ring-closing metathesis for the construction of the cyclohexenyl ring system. The labeled amino acid was further activated as an SNAc-ester for feeding experiments.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Jun
pubmed:issn
1523-7052
pubmed:author
pubmed:copyrightInfo
© 2011 American Chemical Society
pubmed:issnType
Electronic
pubmed:day
17
pubmed:volume
13
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
3210-3
pubmed:meshHeading
pubmed:year
2011
pubmed:articleTitle
Stereoselective synthesis of deuterated ?-cyclohexenylserine, a biosynthetic intermediate of the salinosporamides.
pubmed:affiliation
Universita?t des Saarlandes, Institut fu?r Organische Chemie, Im Stadtwald, Geb. C4.2, D-66123 Saarbru?cken, Germany.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't