Linked Life Data

21589538

Source:http://linkedlifedata.com/resource/pubmed/id/21589538

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
Pt 12
pubmed:dateCreated
2011-5-18
pubmed:abstractText
The shape of the title compound, C(19)H(21)N(3)O(6), is curved with the conformation about the imine bond [1.291?(3)?Å] being E. While the hy-droxy-substituted benzene ring is almost coplanar with the hydrazinyl residue [N-N-C-C = 177.31?(18)°], an observation correlated with an intra-molecular O-H?N hydrogen bond leading to an S(6) ring, the remaining residues exhibit significant twists. The carbonyl residues are directed away from each other as are the amines. This allows for the formation of O-H?O and N-H?O hydrogen bonds in the crystal, which lead to two-dimensional supra-molecular arrays in the ac plane. Additional stabilization to the layers is afforded by C-H?? inter-actions.
pubmed:commentsCorrections
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:issn
1600-5368
pubmed:author
pubmed:issnType
Electronic
pubmed:volume
66
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
o3253-4
pubmed:dateRevised
2011-11-11
pubmed:year
2010
pubmed:articleTitle
Benzyl N-[(S)-2-hy-droxy-1-({[(E)-2-hy-droxy-4-meth-oxy-benzyl-idene]hydrazin-yl}carbon-yl)eth-yl]carbamate.
pubmed:publicationType
Journal Article