Linked Life Data

21589247

Source:http://linkedlifedata.com/resource/pubmed/id/21589247

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
Pt 12
pubmed:dateCreated
2011-5-18
pubmed:abstractText
In the title compound, [AgBr(C(7)H(10)N(2))](n), adjacent Ag(I) atoms are bridged by bidentate CNCH(2)C(CH(3))(2)CH(2)NC ligands via the NC groups, forming [Ag{CNCH(2)C(CH(3))(2)CH(2)NC}](n) chains with the metal atom in a distorted tetrahedral coordination. The bromide counter-anions cross-link the Ag(I) atoms of the chains, forming a two-dimensional polymeric network {[Ag(I)(CNCH(2)C(CH(3))(2)CH(2)NC)]Br}(n) extend-ing parallel to (010). The polymeric structure is similar to that of the very recently reported Cl(-), I(-) and NO(3) (-) analogues. This gives a strong indication that 2,2-dimethyl-propane-1,3-diyl diisocyanide is a potential ligand for giving polymeric structures on treatment with AgX (X = Cl(-), Br(-), I(-) or NO(3) (-)) regardless of the counter-anion used.
pubmed:commentsCorrections
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:issn
1600-5368
pubmed:author
pubmed:issnType
Electronic
pubmed:volume
66
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
m1555-6
pubmed:dateRevised
2011-11-11
pubmed:year
2010
pubmed:articleTitle
Poly[?-bromido-?-(2,2-dimethyl-propane-1,3-diyl diisocyanide)-silver(I)]: a powder diffraction study.
pubmed:affiliation
Department of Chemistry, Atomic Energy Commission of Syria (AECS), PO Box 6091, Damascus, Syrian Arab Republic.
pubmed:publicationType
Journal Article