Source:http://linkedlifedata.com/resource/pubmed/id/21588893
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
Pt 11
|
| pubmed:dateCreated |
2011-5-18
|
| pubmed:abstractText |
In the title complex, [Mn(3)(CH(3)CO(2))(6)(C(2)H(6)SO)(2)](n), the Mn(II) ions exhibit similar MnO(6) octa-hedral coordination geometries but with different coordination environments. One type of Mn(II) ion is surrounded by five acetate groups and a terminal dimethyl sulfoxide group, while the other lies on a twofold axis and is coordinated by six O atoms from three symmetry-related acetate ions. The acetate anions exhibit three independent bridging modes, which flexibly bridge the Mn(II) ions along the c-axis direction, forming an infinite chain structure; the chains are further inter-connected through weak C-H?O and C-H?S hydrogen-bonding inter-actions.
|
| pubmed:commentsCorrections | |
| pubmed:language |
eng
|
| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:issn |
1600-5368
|
| pubmed:author | |
| pubmed:issnType |
Electronic
|
| pubmed:volume |
66
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| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
m1478
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| pubmed:dateRevised |
2011-11-11
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| pubmed:year |
2010
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| pubmed:articleTitle |
Poly[hexa-?-acetato-bis-(dimethyl sulfoxide)-trimanganese(II)].
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| pubmed:publicationType |
Journal Article
|