Source:http://linkedlifedata.com/resource/pubmed/id/21588537
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
Pt 9
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| pubmed:dateCreated |
2011-5-18
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| pubmed:abstractText |
In the title complex, [Co(C(5)HF(6)O(2))(2)(C(12)H(9)BrN(2))], the Co(II) atom exhibits a pseudo-octa-hedral coordination geometry, comprising two N-donor atoms from a bidentate chelate (4-bromo-phen-yl)(2-pyridyl-methyl-idene)amine (ppa(Br)) ligand [Co-N = 2.098?(2) and 2.209?(2)?Å] and four O-donor atoms from two bidentate chelate 1,1,1,5,5,5-hexa-fluoro-pentane-2,4-dionate (hfac) ligands [Co-O range = 2.0452?(19)-2.0796?(19)?Å]. The packing of the structure involves weak ?-? inter-actions between the pyridyl and benzene rings of neighbouring ppa(Br) ligands [centroid-centroid distance = 3.928?(2)?Å] and inter-actions between the Br atom on the ppa(Br) ligand and the hfac ligand [Br?C = 3.531?(2)?Å].
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| pubmed:commentsCorrections | |
| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:issn |
1600-5368
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| pubmed:author | |
| pubmed:issnType |
Electronic
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| pubmed:volume |
66
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
m1138-9
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| pubmed:dateRevised |
2011-11-11
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| pubmed:year |
2010
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| pubmed:articleTitle |
[(4-Bromo-phen-yl)(2-pyridyl-methyl-idene)amine-?N,N']bis-(1,1,1,5,5,5-hexa-fluoro-pentane-2,4-dionato-?O,O')cobalt(II).
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| pubmed:publicationType |
Journal Article
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