Source:http://linkedlifedata.com/resource/pubmed/id/21584033
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| Predicate | Object |
|---|---|
| rdf:type | |
| pubmed:issue |
Pt 5
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| pubmed:dateCreated |
2011-5-17
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| pubmed:abstractText |
In the structure of the title compound, C(10)H(11)BrN(4), the plane of the substituted 1,2,3-triazole ring is tilted by 14.84?(10)° with respect to the mean plane of the pyridine ring. The pyridine and closest triazole N atoms adopt an anti arrangement which removes any lone pair-lone pair repulsions between the N atoms. This conformation is further stabilized by weak intermolecular C-H?N inter-actions. There are two mol-ecules in the unit cell, which form a centrosymmetric head-to-tail dimer. The dimers are stabilized through ?-? inter-actions [centroid-centroid distance = 3.733?(4)?Å and mean inter-planar distance = 3.806?(12)?Å] between the substituted 1,2,3-triazole ring and the pyridine rings in adjacent mol-ecules. Each dimer inter-acts with two neighbouring dimers above and below, forming a slipped stack of dimers through the crystal. The 3-bromo-propyl chain sits over the pyridine ring of a neighbouring mol-ecule and the triazole rings of nearby mol-ecules are adjacent.
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| pubmed:commentsCorrections |
http://linkedlifedata.com/resource/pubmed/commentcorrection/21584033-11975567,
http://linkedlifedata.com/resource/pubmed/commentcorrection/21584033-12037360,
http://linkedlifedata.com/resource/pubmed/commentcorrection/21584033-12203546,
http://linkedlifedata.com/resource/pubmed/commentcorrection/21584033-17594022,
http://linkedlifedata.com/resource/pubmed/commentcorrection/21584033-18156677,
http://linkedlifedata.com/resource/pubmed/commentcorrection/21584033-18300220,
http://linkedlifedata.com/resource/pubmed/commentcorrection/21584033-18443694,
http://linkedlifedata.com/resource/pubmed/commentcorrection/21584033-18463740,
http://linkedlifedata.com/resource/pubmed/commentcorrection/21584033-18496819,
http://linkedlifedata.com/resource/pubmed/commentcorrection/21584033-18560661,
http://linkedlifedata.com/resource/pubmed/commentcorrection/21584033-18698735
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:issn |
1600-5368
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| pubmed:author | |
| pubmed:issnType |
Electronic
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| pubmed:volume |
65
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
o999-o1000
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| pubmed:dateRevised |
2011-11-11
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| pubmed:year |
2009
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| pubmed:articleTitle |
1-(3-Bromo-prop-yl)-4-(2-pyrid-yl)-1H-1,2,3-triazole.
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| pubmed:affiliation |
Department of Chemistry, University of Otago, PO Box 56, Dunedin, New Zealand.
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| pubmed:publicationType |
Journal Article
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