Source:http://linkedlifedata.com/resource/pubmed/id/21583038
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
Pt 6
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| pubmed:dateCreated |
2011-5-17
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| pubmed:abstractText |
The title compound, [Ni(C(11)H(10)N(2)O(2))(2)](NO(3))(2), consists of an Ni(II) atom coordinated by two tridentate chelating di-2-pyridylmethane-diol [(2-py)(2)C(OH)(2)] ligands. The Ni(II) atom is located on an inversion center. The geometry around the Ni(II) atom is distorted octa-hedral. The gem-diol (2-py)(2)C(OH)(2) ligand adopts the coordination mode ?(1):?(1):?(1). The Ni-N and Ni-O bond lengths are typical for high-spin Ni(II) in an octa-hedral environment [Ni-N = 2.094?(2) and 2.124?(3)?Å, and Ni-O = 2.108?(3)?Å]. One of the hydr-oxy H atoms is split over two positions which both inter-act with the nitrate anion. The occurence of different O-H?O hydrogen bonds leads to the formation of a layer parallel to the (101) plane.
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| pubmed:commentsCorrections | |
| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:issn |
1600-5368
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| pubmed:author | |
| pubmed:issnType |
Electronic
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| pubmed:volume |
65
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
m678-9
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| pubmed:dateRevised |
2011-11-11
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| pubmed:year |
2009
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| pubmed:articleTitle |
Bis(di-2-pyridylmethane-diol-?N,O,N')nickel(II) dinitrate.
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| pubmed:publicationType |
Journal Article
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