Source:http://linkedlifedata.com/resource/pubmed/id/21582995
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| Predicate | Object |
|---|---|
| rdf:type | |
| pubmed:issue |
Pt 6
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| pubmed:dateCreated |
2011-5-17
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| pubmed:abstractText |
The microwave solvothermal reaction of nickel nitrate with trimesic acid provided the title compound, [Ni(3)(BTC)(2)(H(2)O)(12)](n) (BTC = benzene-1,3,5-tricarboxyl-ate anion, C(9)H(3)O(6)), which is a metal coordination polymer composed of one-dimensional zigzag chains. The crystal under investigation was ramecically twinned with an approximate twin domain ratio of 1:1. In the asymmetric unit, there are two types of Ni atoms. One of the NiO(6) groups (2 symmetry) is coordinated to only one carboxyl-ate group and thus terminal, the other is bridging, forming the coordination polymer. The extended chains are connected by the organic BTC anions via ?(2)-linkages. O-H?O hydrogen bonds and ?-? inter-actions between the chains [centroid-centroid distance 3.58?(1)?Å] induce the complex to mimic a three-dimensional structure.
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| pubmed:commentsCorrections | |
| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:issn |
1600-5368
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| pubmed:author | |
| pubmed:issnType |
Electronic
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| pubmed:volume |
65
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
m625-6
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| pubmed:dateRevised |
2011-11-11
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| pubmed:year |
2009
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| pubmed:articleTitle |
catena-Poly[[tetraaquanickel(II)]-?(3)-benzene-1,3,5-tricarboxylato-3':1:2-?O:O,O:O-[tetraaquanickel(II)]-?(2)-benzene-1,3,5-tricarboxylato-2:3?O:O-[tetraaquanickel(II)]].
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| pubmed:affiliation |
Department of Chemistry, Chung-Yuan Christian University, Chung-Li 320, Taiwan.
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| pubmed:publicationType |
Journal Article
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