Source:http://linkedlifedata.com/resource/pubmed/id/21581178
Switch to
| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
Pt 12
|
| pubmed:dateCreated |
2011-5-17
|
| pubmed:abstractText |
The title compound, [Cu(2)(CN)(SCN)(C(10)H(8)N(2))(2)](n), contains two crystallographically independent Cu(I) atoms, each in a distorted tetra-hedral geometry. Each Cu atom is coordinated by a bidentate chelating 2,2'-bipyridine ligand. A bridging cyanide anion links the two Cu(2,2'-bipyridine) units to form a binuclear unit. Adjacent binuclear units are connected by a thio-cyanate anion into a one-dimensional helical chain along [010]. The cyanide anion is disordered, with each site occupied by both C and N atoms in an occupancy ratio of 0.61?(5):0.39?(5). The S atom of the thio-cyanate anion is also disordered over two sites, with occupancy factors of 0.61?(3) and 0.39?(3). There are ?-? inter-actions between the pyridyl rings of neighbouring chains [centroid-centroid distance = 3.82?(1)?Å].
|
| pubmed:commentsCorrections | |
| pubmed:language |
eng
|
| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:issn |
1600-5368
|
| pubmed:author | |
| pubmed:issnType |
Electronic
|
| pubmed:volume |
64
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
m1576
|
| pubmed:dateRevised |
2011-11-11
|
| pubmed:year |
2008
|
| pubmed:articleTitle |
catena-Poly[[(2,2'-bipyridine-?N,N')copper(I)]-?-cyanido-?C:N-[(2,2'-bipyridine-?N,N')copper(I)]-?-thio-cyanato-?S:N].
|
| pubmed:affiliation |
College of Mechanical and Material Engineering, Functional Materials Research Institue, Three Gorges University, Yichang 443002, People's Republic of China.
|
| pubmed:publicationType |
Journal Article
|