Source:http://linkedlifedata.com/resource/pubmed/id/21580551
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| Predicate | Object |
|---|---|
| rdf:type | |
| pubmed:issue |
Pt 4
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| pubmed:dateCreated |
2011-5-17
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| pubmed:abstractText |
The title compound, (C(10)H(10)N(2))[Sb(2)(C(7)H(2)NO(5))(2)(OH)(2)(H(2)O)(2)]·2H(2)O, consists of a binuclear anion, a diprotonated 4,4'-bipyridinium cation and two uncoordinated water mol-ecules. Each Sb(III) atom is six-coordinated by one chelating 4-oxidopyridine-2,6-dicarboxyl-ate ligand, one water mol-ecule, one OH group and one bridging O atom from a neighboring carboxyl-ate group in a distorted penta-gonal-pyramidal geometry, with the OH group at the apical position. The two pyridine rings in the bipyridinium cation are twisted with respect to each other, making a dihedral angle of 22.7?(1)°. The cations are connected to the anions by N-H?O hydrogen bonds, forming a chain. The coordinated water mol-ecules form hydrogen bonds with the oxido O atoms of the anion, building a two-dimensional sheet, which is further connected into a three-dimensional structure by O-H?O and C-H?O hydrogen bonds and C=O?? inter-actions [O?centroid distances = 3.1785?(17), 3.4737?(19) and 3.5685?(19)?Å].
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| pubmed:commentsCorrections | |
| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:issn |
1600-5368
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| pubmed:author | |
| pubmed:issnType |
Electronic
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| pubmed:volume |
66
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
m467-8
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| pubmed:dateRevised |
2011-11-11
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| pubmed:year |
2010
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| pubmed:articleTitle |
4,4'-Bipyridinium bis-(?-4-oxo-1,4-dihydropyridine-2,6-dicarboxyl-ato)bis-[aqua-hydroxido-anti-monate(III)] dihydrate.
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| pubmed:publicationType |
Journal Article
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