Source:http://linkedlifedata.com/resource/pubmed/id/21580463
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| Predicate | Object |
|---|---|
| rdf:type | |
| pubmed:issue |
Pt 4
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| pubmed:dateCreated |
2011-5-17
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| pubmed:abstractText |
The title compound, {[Na(H(2)O)(4)](6)[V(10)O(28)]·2H(2)O}(n), crystallized from a H(2)O/THF/CH(3)CN solution (pH ca 6) containing equimolar amounts of NaVO(3) and N-(2-hydroxy-benz-yl)-N-(2-picol-yl)glycine. In the crystal structure, the deca-vanadate [V(10)O(28)](6-) anion ( symmetry) is coordinated, via four terminal oxide ligands of V centres, to two dinuclear [{Na(H(2)O)(3)}(2)(?-H(2)O)(2)](2+) units. Inter-connection of these aquasodium-ion-sandwiched deca-vanadates to chains parallel to [001] is effected by ?-[{Na(H(2)O)(3)}(2)(?-H(2)O)(2)](2+) units, bridging adjacent deca-vanadates via O=V. The structure is consolidated by an extensive network of O-H?O hydrogen bonds.
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| pubmed:commentsCorrections | |
| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:issn |
1600-5368
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| pubmed:author | |
| pubmed:issnType |
Electronic
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| pubmed:volume |
66
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
i30-i31
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| pubmed:dateRevised |
2011-11-11
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| pubmed:year |
2010
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| pubmed:articleTitle |
Hexakis(tetra-aqua-sodium) deca-vanadate(V) dihydrate.
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| pubmed:publicationType |
Journal Article
|