Statements in which the resource exists as a subject.
PredicateObject
rdf:type
pubmed:issue
Pt 3
pubmed:dateCreated
2011-5-17
pubmed:abstractText
In the title salt, (C(17)H(17)F(6)N(2)O)(2)[Sn(C(6)H(5))(2)Cl(4)], the complete anion is generated by crystallograaphic inversion symmetry, giving a trans-SnC(2)Cl(4) octa-hedral coordination geometry for the metal atom. In the cation, the quinoline residue is almost normal to the other atoms, so that the ion has an L-shaped conformation [the C-C-C-C torsion angle linking the fused-ring systems is 100.9?(7)°]; the six-membered piperidin-1-ium ring has a chair conformation. An intra-molecular N-H?O inter-action occurs. In the crystal, N-H?Cl and O-H?Cl hydrogen bonds link the components into a supra-molecular chain propagating along the a axis. C-H?Cl inter-actions are also present.
pubmed:commentsCorrections
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:issn
1600-5368
pubmed:author
pubmed:issnType
Electronic
pubmed:volume
66
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
m336-7
pubmed:dateRevised
2011-11-11
pubmed:year
2010
pubmed:articleTitle
Bis(2-{[2,8-bis-(trifluoro-meth-yl)quinolin-4-yl](hydr-oxy)meth-yl}piperidin-1-ium) tetra-chloridodiphenyl-stannate(IV).
pubmed:publicationType
Journal Article