Source:http://linkedlifedata.com/resource/pubmed/id/21579543
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| Predicate | Object |
|---|---|
| rdf:type | |
| pubmed:issue |
Pt 6
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| pubmed:dateCreated |
2011-5-17
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| pubmed:abstractText |
In the title compound, C(21)H(20)N(2)O(3), the naphthalimide unit is almost planar (r.m.s. deviation for the 15 non-H atoms = 0.059?Å). The carboximide N atom and the five C atoms of the 2-methyl-prop-2-enoyl substituent also lie in a plane (r.m.s. deviation = 0.009?Å), which subtends an angle of 84.34?(7)° to the naphthalamide plane. This orients the =CH(2) group of the vinyl fragment towards the naphthalimide rings, giving the mol-ecule an extended configuration. The piperidine ring adopts a chair conformation and there is evidence for some delocalization between the naphthalene and piperidine units, the C-N(pip) bond length being 1.404?(4)?Å. In the crystal structure, ?-? contacts with centroid-centroid distances of 3.5351?(18) and 3.7794?(18)?Å supported by C-H?O hydrogen bonds link adjacent mol-ecules in a head-to-tail fashion, forming dimers. These are further stabilized by other C-H?O contacts of varying strength, which stack the mol-ecules down the b axis.
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| pubmed:commentsCorrections | |
| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:issn |
1600-5368
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| pubmed:author | |
| pubmed:issnType |
Electronic
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| pubmed:volume |
66
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
o1476-7
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| pubmed:dateRevised |
2011-11-11
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| pubmed:year |
2010
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| pubmed:articleTitle |
N-Methacryloyl-4-(piperidin-1-yl)-1,8-naphthalimide.
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| pubmed:affiliation |
Department of Chemistry, University of Otago, PO Box 56, Dunedin, New Zealand.
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| pubmed:publicationType |
Journal Article
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