Source:http://linkedlifedata.com/resource/pubmed/id/21522821
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
Pt 2
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| pubmed:dateCreated |
2011-4-27
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| pubmed:abstractText |
The title complex, [Zn(CH(5)N(3)S)(2)(C(2)H(6)OS)](C(6)H(2)N(3)O(7))(2)·C(2)H(6)OS·H(2)O, is composed of a [Zn(thio-semi-carbazide)(2)(DMSO)](2+) cation (where DMSO is dimethyl sulfoxide), and two picrate anions. In the asymmetric unit, there is also a solvent mol-ecule of DMSO and a water mol-ecule of crystallization. In the cation, the Zn(II) atom is five-coordinated in a distorted square-pyramidal geometry. It coordinates to the O atom of a DMSO mol-ecule and to the S and one N atom of two thio-semicarbazide mol-ecules, which behave as bidentate ligands coordinating in a trans arrangement. In the crystal, a number of N-H?O, O-H?O and N-H?S hydrogen bonds link the mol-ecules into two-dimensional networks. These networks are further linked via weak C-H?O inter-actions, forming a three-dimensional arrangement. Positional disorder in one methyl group of the coordinated DMSO molecule and in the two picrate anions was observed.
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| pubmed:commentsCorrections | |
| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:issn |
1600-5368
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| pubmed:author | |
| pubmed:issnType |
Electronic
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| pubmed:volume |
67
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
m133-4
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| pubmed:dateRevised |
2011-11-11
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| pubmed:year |
2011
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| pubmed:articleTitle |
(Dimethyl sulfoxide-?O)bis-(thio-semicarbazide-?N,S)zinc dipicrate dimethyl sulfoxide solvate monohydrate.
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| pubmed:publicationType |
Journal Article
|