Source:http://linkedlifedata.com/resource/pubmed/id/21522286
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| Predicate | Object |
|---|---|
| rdf:type | |
| pubmed:issue |
Pt 3
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| pubmed:dateCreated |
2011-4-27
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| pubmed:abstractText |
In the centrosymmetric dinuclear complex anion of the title compound, (C(5)H(8)N(3))(2)[Bi(2)(C(7)H(3)NO(4))(4)(H(2)O)(2)]·4H(2)O, the Bi(III) atom is eight-coordinated in an N(2)O(6) environment and has a distorted bicapped trigonal-prismatic coordination environment. Extensive inter-molecular O-H?O, N-H?O and weak C-H?O hydrogen bonds lead to the stability of the crystal structure. Inter-actions between one C-H group of the 2,3-diamino-pyridinium [(2,3-dapyH)(+)] cation and the aromatic ring of the pyridine-2,6-dicarboxyl-ate (pydc) ligand (C-H?centroid distance = 2.78?Å) and ?-? inter-actions between the (2,3-dapyH)(+) cations and between the (2,3-dapyH)(+) cation and the pydc ligand [centroid-centroid distances = 3.489?(5) and 3.694?(5)?Å] are observed.
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| pubmed:commentsCorrections | |
| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:issn |
1600-5368
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| pubmed:author | |
| pubmed:issnType |
Electronic
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| pubmed:volume |
67
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
m360-1
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| pubmed:dateRevised |
2011-11-11
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| pubmed:year |
2011
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| pubmed:articleTitle |
Bis(2,3-diamino-pyridinium) bis-(?-pyridine-2,6-dicarboxyl-ato)-?O,N,O:O;?O:O,N,O-bis-[aqua-(pyridine-2,6-dicarboxyl-ato-?O,N,O)bis-muthate(III)] tetra-hydrate.
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| pubmed:publicationType |
Journal Article
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