Source:http://linkedlifedata.com/resource/pubmed/id/21522248
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
Pt 3
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pubmed:dateCreated |
2011-4-27
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pubmed:abstractText |
The title Schiff base zinc(II) complex, [Zn(C(13)H(10)ClN(2)O)I(CH(3)OH)], was synthesized by the reaction of 5-chloro-salicyl-aldehyde, 2-amino-methyl-pyridine and zinc iodide in methanol. The Zn(II) atom is five-coordinated by one phenolate O atom, one imine and one pyridine N atom of the Schiff base ligand, one methanol O atom and one I atom, forming a distorted square-pyramidal geometry, with the I atom at the apical site. The dihedral angle between the benzene and pyridine rings is 22.9?(2)°. In the crystal, centrosymmetrically related mol-ecules are linked through inter-molecular O-H?O hydrogen bonds, forming dimers.
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pubmed:commentsCorrections | |
pubmed:language |
eng
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pubmed:journal | |
pubmed:status |
PubMed-not-MEDLINE
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pubmed:issn |
1600-5368
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pubmed:author | |
pubmed:issnType |
Electronic
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pubmed:volume |
67
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
m313
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pubmed:dateRevised |
2011-11-11
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pubmed:year |
2011
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pubmed:articleTitle |
(4-Chloro-2-{[(pyridin-2-ylmeth-yl)imino]-meth-yl}phenolato)iodido(methanol)zinc(II).
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pubmed:affiliation |
College of Chemistry and Biology Engineering, Yichun University, Yichun 336000, People's Republic of China.
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pubmed:publicationType |
Journal Article
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