Source:http://linkedlifedata.com/resource/pubmed/id/21506523
Switch to
| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
10
|
| pubmed:dateCreated |
2011-5-9
|
| pubmed:abstractText |
Liquid crystalline (LC) platinum(II) complexes with 1,2-thiophenolato and 1,2-benzendithiolato have been newly synthesized and investigated by spectroscopy together with the catecholato analogue. The variations in coordinating atoms (O or S or O/S mixed) lead to significant modulation in electrochemical properties in solution and absorption and emission properties of the complexes both in solution media and in the condensed phases. The asymmetric, polar mesogens/chromophores consisting of Pt(II), redox-active ligands, and alkyl-substituted bipyridine commonly play important roles not only in stabilizing the columnar LC phases, but also in fluctuations of the ground state energies. A key finding of the present work is the chromic properties of LC complexes induced by the interplay of self-association of the mesogens/chromophores and their fluctuating properties.
|
| pubmed:language |
eng
|
| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:month |
May
|
| pubmed:issn |
1520-510X
|
| pubmed:author | |
| pubmed:issnType |
Electronic
|
| pubmed:day |
16
|
| pubmed:volume |
50
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
4279-88
|
| pubmed:year |
2011
|
| pubmed:articleTitle |
Chromic behaviors of hexagonal columnar liquid crystalline platinum complexes with catecholato, 2-thiophenolato, and benzenedithiolato.
|
| pubmed:affiliation |
Division of Chemistry, Faculty of Science, Hokkaido University, North 10, West 8, Kita-ku, Sapporo 060-0810, Japan. chang@sci.hokudai.ac.jp
|
| pubmed:publicationType |
Journal Article
|