Source:http://linkedlifedata.com/resource/pubmed/id/21503303
Switch to
| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
20
|
| pubmed:dateCreated |
2011-5-4
|
| pubmed:abstractText |
By changing the ratio of reactants, two mononuclear Dy complexes, [Dy(phen)(acac)(3)] (1) and [Dy(phen)(2)(NO(3))(2)(acac)]·H(2)O (2) have been synthesized and structurally characterized. In 1, a Dy atom bearing square-antiprism coordination geometry exhibits SMM behaviour, while compound 2 with a bicapped-square-antiprism geometry does not show such SMM properties. The different magnetic behaviours seen in 1 and 2 are probably due to a different coordination environment and ligand field around the Dy(III) ions. The results proved the important influence of the structural environment of a SMM on its magnetic behaviour.
|
| pubmed:language |
eng
|
| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:month |
May
|
| pubmed:issn |
1477-9234
|
| pubmed:author | |
| pubmed:issnType |
Electronic
|
| pubmed:day |
28
|
| pubmed:volume |
40
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
5579-83
|
| pubmed:year |
2011
|
| pubmed:articleTitle |
Coordination-perturbed single-molecule magnet behaviour of mononuclear dysprosium complexes.
|
| pubmed:affiliation |
Department of Chemistry and Key Laboratory of Advanced Energy Materials Chemistry, Nankai University, Tianjin 300071, P. R. China.
|
| pubmed:publicationType |
Journal Article
|