21500851

Source:http://linkedlifedata.com/resource/pubmed/id/21500851

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0010546, umls-concept:C0260127, umls-concept:C0596311, umls-concept:C1330957
pubmed:issue	18
pubmed:dateCreated	2011-5-4
pubmed:abstractText	It has been established that a cationic rhodium(I)/(R)-H(8)-BINAP or (R)-Segphos complex catalyzes two modes of enantioselective cyclizations of ?-alkynylaldehydes with acyl phosphonates via C-P or C-H bond cleavage. The ligands of the Rh(I) complexes and the substitutents of both ?-alkynylaldehydes and acyl phosphonates control these two different pathways.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/7503056
pubmed:status	PubMed-not-MEDLINE
pubmed:month	May
pubmed:issn	1520-5126
pubmed:author	pubmed-author:MasudaKengoK, pubmed-author:NoguchiKeiichiK, pubmed-author:SakiyamaNorifumiN, pubmed-author:TanakaKenK, pubmed-author:TanakaRieR
pubmed:copyrightInfo	© 2011 American Chemical Society
pubmed:issnType	Electronic
pubmed:day	11
pubmed:volume	133
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	6918-21
pubmed:year	2011
pubmed:articleTitle	Rhodium-catalyzed enantioselective cyclizations of ?-alkynylaldehydes with acyl phosphonates: ligand- and substituent-controlled C-P or C-H bond cleavage.
pubmed:affiliation	Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology, Koganei, Tokyo 184-8588, Japan.
pubmed:publicationType	Journal Article