Linked Life Data

21491516

Source:http://linkedlifedata.com/resource/pubmed/id/21491516

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
21
pubmed:dateCreated
2011-5-10
pubmed:abstractText
Structural phase-controlled formation of binary Co(2)P and CoP nanocrystals is achieved by reacting cobalt(II) oleate with trioctylphosphine. In the absence of oleylamine, Co(2)P nanowires are formed at both 290 and 320 °C. In the presence of oleylamine, Co(2)P nanorods are formed at 290 °C, and CoP nanorods are formed at 320 °C. With the simultaneous reaction of iron(III) oleate and cobalt(II) oleate with trioctylphosphine in the presence of oleylamine, ternary Co(2)P-type cobalt-iron phosphide nanostructures are produced at both 290 and 320 °C, corresponding to rice-shaped Co(1.5)Fe(0.5)P nanorods and split Co(1.7)Fe(0.3)P nanostructures, respectively. The controlled incorporation of iron into cobalt phosphide can alter the magnetic properties from paramagnetic binary Co(2)P to ferromagnetic Co(2)P-type ternary cobalt-iron phosphide nanostructures. Meanwhile, the time-dependent morphological evolution from small nanodots/nanorods, through seeded growth to unique split nanostructures is demonstrated in one-pot reaction at 320 °C.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
May
pubmed:issn
1521-3765
pubmed:author
pubmed:copyrightInfo
Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
pubmed:issnType
Electronic
pubmed:day
16
pubmed:volume
17
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
5982-8
pubmed:meshHeading
pubmed:year
2011
pubmed:articleTitle
Ternary cobalt-iron phosphide nanocrystals with controlled compositions, properties, and morphologies from nanorods and nanorice to split nanostructures.
pubmed:affiliation
Institute of Materials Research and Engineering, 3 Research Link, A*STAR (Agency for Science, Technology and Research), Singapore 117602, Singapore.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't