Source:http://linkedlifedata.com/resource/pubmed/id/21468404
Switch to
| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
6
|
| pubmed:dateCreated |
2011-6-2
|
| pubmed:abstractText |
A simple strategy that is based on conversion of an electron-rich pyridyl to an electron-deficient pyridinium ion is able to orient thirteen of the sixteen olefins investigated towards a single dimer in quantitative yield in the crystalline state. The reagent used is HCl, the method involves grinding the olefin with a drop of HCl and the dimerization is achieved by exposure of the crystalline stilbazolium·HCl salts to light. The weak force involved in modifying the crystal packing is most likely charge-transfer interaction.
|
| pubmed:language |
eng
|
| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:month |
Jun
|
| pubmed:issn |
1474-9092
|
| pubmed:author | |
| pubmed:issnType |
Electronic
|
| pubmed:volume |
10
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
891-4
|
| pubmed:year |
2011
|
| pubmed:articleTitle |
Photodimerization of HCl salts of azastilbenes in the solid state.
|
| pubmed:affiliation |
Department of Chemistry, University of Miami, Coral Gables, FL 33146, USA.
|
| pubmed:publicationType |
Journal Article
|