Linked Life Data

21456531

Source:http://linkedlifedata.com/resource/pubmed/id/21456531

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
10
pubmed:dateCreated
2011-5-13
pubmed:abstractText
Through a biomimetic pathway, hyperolactone D, 4-hydroxyhyperolactone D, and hyperolactone C were synthesized from methyl acetoacetate via Weiler's dianion method, asymmetric allylic alkylation, biomimetic lactonization, oxidation, and cyclization. The stereochemistry of the quaternary carbon was controlled efficiently by Palladium-catalyzed asymmetric allylic alkylation. This strategy was also used for the synthesis of hyperolactone B.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
May
pubmed:issn
1520-6904
pubmed:author
pubmed:issnType
Electronic
pubmed:day
20
pubmed:volume
76
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
4075-81
pubmed:meshHeading
pubmed:year
2011
pubmed:articleTitle
Biomimetic synthesis of hyperolactones.
pubmed:affiliation
State Key Laboratory of Applied Organic Chemistry & College of Chemistry and Chemical Engineering, Lanzhou University, 222 Tianshui South Road, Lanzhou, Gansu 730000, China.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't