21437326

Source:http://linkedlifedata.com/resource/pubmed/id/21437326

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0022203, umls-concept:C0023688, umls-concept:C0054666, umls-concept:C0079411, umls-concept:C1704241, umls-concept:C2825407
pubmed:issue	18
pubmed:dateCreated	2011-4-21
pubmed:abstractText	The first example of the diastereoselective synthesis induced by anomeric isomerism of sugar units in ligands of metal complexes was demonstrated. S and R configurations of chiral-at-metal Ir(III) and Rh(III) complexes were selectively obtained by using chelate-type NHC ligands with ?- and ?-glucopyranosyl units, respectively.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/101176026
pubmed:status	PubMed-not-MEDLINE
pubmed:month	May
pubmed:issn	1477-9234
pubmed:author	pubmed-author:HashimotoHidekiH, pubmed-author:KinoshitaIsamuI, pubmed-author:NishiokaTakanoriT, pubmed-author:ShibataTeppeiT, pubmed-author:YanoShigenobuS
pubmed:issnType	Electronic
pubmed:day	14
pubmed:volume	40
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	4826-9
pubmed:year	2011
pubmed:articleTitle	Unprecedented diastereoselective generation of chiral-at-metal, half sandwich Ir(III) and Rh(III) complexes via anomeric isomerism on "sugar-coated" N-heterocyclic carbene ligands.
pubmed:affiliation	Department of Chemistry, Graduate School of Science, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan.
pubmed:publicationType	Journal Article