Linked Life Data

21433174

Source:http://linkedlifedata.com/resource/pubmed/id/21433174

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
3
pubmed:dateCreated
2011-3-24
pubmed:abstractText
Hybrid nanoparticles with a silica core and grafted poly(methyl methacrylate) (PMMA) or poly(n-butyl methacrylate) (PBMA) chains were prepared via activators generated by electron transfer for atom transfer radical polymerization (AGET ATRP) at room temperature under high pressure. Due to enhanced propagation rate constant and reduced termination rate constant for polymerizations conducted under high pressure, the rate of polymerization was increased, while preserving good control over polymerization when compared to ATRP under ambient pressure. Molecular weights of greater than 1 million were obtained. The PMMA and PBMA brushes exhibited "semi-diluted" or "diluted" brush architecture with the highest grafting densities ?0.3 chain·nm(-2).
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Feb
pubmed:issn
1521-3927
pubmed:author
pubmed:copyrightInfo
Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
pubmed:issnType
Electronic
pubmed:day
2
pubmed:volume
32
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
295-301
pubmed:meshHeading
pubmed:year
2011
pubmed:articleTitle
Silica-polymethacrylate hybrid particles synthesized using high-pressure atom transfer radical polymerization.
pubmed:affiliation
Institute of Polymer and Dye Technology, Technical University of Lodz, ul Stefanowskiego 12/16, 90-924 Lodz, Poland. joanna.pietrasik@p.lodz.pl
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't