Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
5
pubmed:dateCreated
2011-3-16
pubmed:abstractText
This paper reviewed different analytical techniques to determine concentrations of the environmentally-friendly oxidant ferrate(VI) (Fe(VI)O(2-)(4), Fe(VI)) anion in solid and solution samples. The techniques included volumetric (chromite and arsenite), electrochemical (cyclic voltammetry and potentiometry), and spectrophotometric methods (Fourier transform infrared, Mossbauer, UV-Visible, 2,2-azino-bis(3-ethylbenzothiazoline-6-sulfonate (ABTS), and fluorescence). The importance of the techniques were briefly described. This paper also presented a newly developed method for the determination of low concentrations (0.25 ?M) of Fe(VI)) using the reaction between Fe(VI) and iodide (I(-)), which formed the yellowish color of I(-)(3) that could be measured spectrophotometrically at 351 nm. The increase in I(-)(3) was linear with respect to Fe(VI) added (0.25-76 ?M) in buffered solutions at pH 5.5-9.3. The linearity was not affected by the ions present in tap water.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Apr
pubmed:issn
1532-4117
pubmed:author
pubmed:issnType
Electronic
pubmed:volume
46
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
453-60
pubmed:meshHeading
pubmed:year
2011
pubmed:articleTitle
Methodologies for the analytical determination of ferrate(VI): a review.
pubmed:affiliation
College of Chemistry and Chemical Engineering, Chongqing University, Chongqing, China.
pubmed:publicationType
Journal Article, Comparative Study, Research Support, U.S. Gov't, Non-P.H.S., Review, Research Support, Non-U.S. Gov't