Linked Life Data

21394351

Source:http://linkedlifedata.com/resource/pubmed/id/21394351

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
16
pubmed:dateCreated
2011-4-6
pubmed:abstractText
Two diferrous complexes, [Fe(2)(?-SCH(2)CH(3))(3)(CO)(5)I] and [Fe(2)(?-SCH(2)CH(2)CH(3))(3)(CO)(5)I] were synthesised via reaction of a monoiron carbonyl precursor, [Fe(CO)(4)I(2)], with ethanethiolate and propanethiolate, respectively. The complexes were fully characterised using spectroscopic techniques, for instance, FTIR and NMR. Their crystal structures were determined using single crystal diffraction analysis. Electrochemical reduction of these complexes are temperature-dependent. At room temperature, the diferrous complexes undergo one-electron reduction. The reduction-initiated cleavage of one bound thiolate and one iodide as a radical, takes the oxidation states of the diiron core from {Fe(I)Fe(II)} to {Fe(I)Fe(I)}. This reduction-initiated transformation can be suppressed by lowering the temperature to 195 K, further reduction of the monoanion was observed at a potential very close to that of the first reduction, which is analogous to the mechanism observed for diiron complexes with a core of {Fe(I)Fe(I)}.
pubmed:grant
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Apr
pubmed:issn
1477-9234
pubmed:author
pubmed:issnType
Electronic
pubmed:day
28
pubmed:volume
40
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
4291-9
pubmed:meshHeading
pubmed:year
2011
pubmed:articleTitle
Diiron carbonyl complexes possessing a {Fe(II)Fe(II)} core: synthesis, characterisation, and electrochemical investigation.
pubmed:affiliation
College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing, 314001, China.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't