Source:http://linkedlifedata.com/resource/pubmed/id/21368402
| Subject | Predicate | Object | Context |
|---|---|---|---|
| pubmed-article:21368402 | rdf:type | pubmed:Citation | lld:pubmed |
| pubmed-article:21368402 | pubmed:issue | Pt 3 | lld:pubmed |
| pubmed-article:21368402 | pubmed:dateCreated | 2011-3-3 | lld:pubmed |
| pubmed-article:21368402 | pubmed:abstractText | The title complexes, hexaaquacobalt(II) bis(?-pyridine-2,6-dicarboxylato)bis[(pyridine-2,6-dicarboxylato)bismuthate(III)] dihydrate, [Co(H(2)O)(6)][Bi(2)(C(7)H(4)NO(4))(4)]·2H(2)O, (I), and hexaaquanickel(II) bis(?-pyridine-2,6-dicarboxylato)bis[(pyridine-2,6-dicarboxylato)bismuthate(III)] dihydrate, [Ni(H(2)O)(6)][Bi(2)(C(7)H(4)NO(4))(4)]·2H(2)O, (II), are isomorphous and crystallize in the triclinic space group P-1. The transition metal ions are located on the inversion centre and adopt slightly distorted MO(6) (M = Co or Ni) octahedral geometries. Two [Bi(pydc)(2)](-) units (pydc is pyridine-2,6-dicarboxylate) are linked via bridging carboxylate groups into centrosymmetric [Bi(2)(pydc)(4)](2-) dianions. The crystal packing reveals that the [M(H(2)O)(6)](2+) cations, [Bi(2)(pydc)(4)](2-) anions and solvent water molecules form multiple hydrogen bonds to generate a supramolecular three-dimensional network. The formation of secondary Bi...O bonds between adjacent [Bi(2)(pydc)(4)](2-) dimers provides an additional supramolecular synthon that directs and facilitates the crystal packing of both (I) and (II). | lld:pubmed |
| pubmed-article:21368402 | pubmed:language | eng | lld:pubmed |
| pubmed-article:21368402 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:21368402 | pubmed:status | PubMed-not-MEDLINE | lld:pubmed |
| pubmed-article:21368402 | pubmed:month | Mar | lld:pubmed |
| pubmed-article:21368402 | pubmed:issn | 1600-5759 | lld:pubmed |
| pubmed-article:21368402 | pubmed:author | pubmed-author:WhitmireKento... | lld:pubmed |
| pubmed-article:21368402 | pubmed:author | pubmed-author:GuleaAurelian... | lld:pubmed |
| pubmed-article:21368402 | pubmed:author | pubmed-author:StavilaVitali... | lld:pubmed |
| pubmed-article:21368402 | pubmed:author | pubmed-author:BulimestruIon... | lld:pubmed |
| pubmed-article:21368402 | pubmed:author | pubmed-author:ColsonAdam... | lld:pubmed |
| pubmed-article:21368402 | pubmed:issnType | Electronic | lld:pubmed |
| pubmed-article:21368402 | pubmed:volume | 67 | lld:pubmed |
| pubmed-article:21368402 | pubmed:owner | NLM | lld:pubmed |
| pubmed-article:21368402 | pubmed:authorsComplete | Y | lld:pubmed |
| pubmed-article:21368402 | pubmed:pagination | m65-8 | lld:pubmed |
| pubmed-article:21368402 | pubmed:year | 2011 | lld:pubmed |
| pubmed-article:21368402 | pubmed:articleTitle | Hexaaquacobalt(II) and hexaaquanickel(II) bis(?-pyridine-2,6-dicarboxylato)bis[(pyridine-2,6-dicarboxylato)bismuthate(III)] dihydrate. | lld:pubmed |
| pubmed-article:21368402 | pubmed:affiliation | Department of Chemistry, Rice University, Houston, TX 77005, USA. | lld:pubmed |
| pubmed-article:21368402 | pubmed:publicationType | Journal Article | lld:pubmed |