Source:http://linkedlifedata.com/resource/pubmed/id/21368402
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| Predicate | Object |
|---|---|
| rdf:type | |
| pubmed:issue |
Pt 3
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| pubmed:dateCreated |
2011-3-3
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| pubmed:abstractText |
The title complexes, hexaaquacobalt(II) bis(?-pyridine-2,6-dicarboxylato)bis[(pyridine-2,6-dicarboxylato)bismuthate(III)] dihydrate, [Co(H(2)O)(6)][Bi(2)(C(7)H(4)NO(4))(4)]·2H(2)O, (I), and hexaaquanickel(II) bis(?-pyridine-2,6-dicarboxylato)bis[(pyridine-2,6-dicarboxylato)bismuthate(III)] dihydrate, [Ni(H(2)O)(6)][Bi(2)(C(7)H(4)NO(4))(4)]·2H(2)O, (II), are isomorphous and crystallize in the triclinic space group P-1. The transition metal ions are located on the inversion centre and adopt slightly distorted MO(6) (M = Co or Ni) octahedral geometries. Two [Bi(pydc)(2)](-) units (pydc is pyridine-2,6-dicarboxylate) are linked via bridging carboxylate groups into centrosymmetric [Bi(2)(pydc)(4)](2-) dianions. The crystal packing reveals that the [M(H(2)O)(6)](2+) cations, [Bi(2)(pydc)(4)](2-) anions and solvent water molecules form multiple hydrogen bonds to generate a supramolecular three-dimensional network. The formation of secondary Bi...O bonds between adjacent [Bi(2)(pydc)(4)](2-) dimers provides an additional supramolecular synthon that directs and facilitates the crystal packing of both (I) and (II).
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Mar
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| pubmed:issn |
1600-5759
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| pubmed:author | |
| pubmed:issnType |
Electronic
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| pubmed:volume |
67
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
m65-8
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| pubmed:year |
2011
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| pubmed:articleTitle |
Hexaaquacobalt(II) and hexaaquanickel(II) bis(?-pyridine-2,6-dicarboxylato)bis[(pyridine-2,6-dicarboxylato)bismuthate(III)] dihydrate.
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| pubmed:affiliation |
Department of Chemistry, Rice University, Houston, TX 77005, USA.
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| pubmed:publicationType |
Journal Article
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