21366293

Source:http://linkedlifedata.com/resource/pubmed/id/21366293

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0001002, umls-concept:C0022634, umls-concept:C0443286, umls-concept:C0761982
pubmed:issue	7
pubmed:dateCreated	2011-3-25
pubmed:abstractText	Enantiomerically enriched trihalomethyl-substituted alcohols having a quaternary chiral carbon center can be prepared by the catalytic enantioselective cross-aldol reaction of acetone with trihalomethyl ketones by using N-(8-quinolinesulfonyl)prolinamide as an organocatalyst. The MO calculations elucidate that the hydrogen bonding between the sulfonimide proton and the 8-quinolyl nitrogen atom plays an important role in exerting the enantioselectivity of the reaction.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/100890393
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Apr
pubmed:issn	1523-7052
pubmed:author	pubmed-author:FunahashiYasuhiroY, pubmed-author:HaraNoriyukiN, pubmed-author:NakamuraShuichiS, pubmed-author:TamuraRyotaR
pubmed:issnType	Electronic
pubmed:day	1
pubmed:volume	13
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	1662-5
pubmed:year	2011
pubmed:articleTitle	N-(heteroarenesulfonyl)prolinamides-catalyzed aldol reaction between acetone and aryl trihalomethyl ketones.
pubmed:affiliation	Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya 466-8555, Japan.
pubmed:publicationType	Journal Article