Linked Life Data

21351177

Source:http://linkedlifedata.com/resource/pubmed/id/21351177

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
13
pubmed:dateCreated
2011-3-11
pubmed:abstractText
Spherical PbSe hollow nanostructure assemblies (HNSAs) were synthesized by a simple one-pot solid/liquid-phase reaction in which solid KPbI(3)?2?H(2)O and SeO(2) are heated in oleic acid/dodecylamine/1-octadecene at 250?°C for 30?min. XRD analysis shows that the obtained product is cubic-phase PbSe and well crystallized. FESEM and TEM images reveal that the obtained spherical PbSe assemblies are made up of small, irregular, and fused hollow nanostructure building blocks. On the basis of temperature- and time-dependent investigations as well as control experiments, molten-salt corrosion of solid PbSe nanocrystal aggregates formed in situ during the high-temperature ripening stage is suggested to explain the formation of such novel assemblies. Moreover, when the reaction temperature is further increased to 280 or 320?°C with other conditions unchanged, cubic and orthorhombic mixed-phase PbSe HNSAs is generated. The obtained PbSe HNSAs exhibit excellent electrogenerated chemiluminescence (ECL) performance. Two strong and stable emission peaks at about -1.4 and +1.5?V (vs. Ag/AgCl) are observed. In particular, the ECL intensity is influenced by the crystal phase of PbSe.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Mar
pubmed:issn
1521-3765
pubmed:author
pubmed:copyrightInfo
Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
pubmed:issnType
Electronic
pubmed:day
21
pubmed:volume
17
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
3739-45
pubmed:meshHeading
pubmed:year
2011
pubmed:articleTitle
Facile synthesis of PbSe hollow nanostructure assemblies via a solid/liquid-phase chemical route and their electrogenerated chemiluminescence properties.
pubmed:affiliation
Jiangsu Key Laboratory of Biofunctional Materials, College of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210097, PR China.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't