|
rdf:type |
|
|
lifeskim:mentions |
umls-concept:C0022023,
umls-concept:C0032521,
umls-concept:C0205838,
umls-concept:C0242414,
umls-concept:C0332298,
umls-concept:C0392747,
umls-concept:C0597635,
umls-concept:C0871261,
umls-concept:C1704632,
umls-concept:C1706817,
umls-concept:C2911692
|
|
pubmed:issue |
6
|
|
pubmed:dateCreated |
2011-3-15
|
|
pubmed:abstractText |
We synthesized new porous coordination polymers (PCPs) {Ln(III)[Co(III)(dcbpy)(3)]·nH(2)O} (Ln = La(3+), Nd(3+), Gd(3+); H(2)dcbpy = 4,4'-dicarboxy-2,2'-bipyridine) and characterized them by X-ray diffraction and vapor-adsorption measurements. These three Ln-Co-based PCPs have similar rock-salt types and highly symmetrical porous structure and show a reversible structural collapse-regeneration accompanied by water-vapor desorption-adsorption. Similar structural regeneration was also observed for the Gd-Co PCP upon exposure to MeOH and CH(3)CN vapors, whereas the remaining two PCPs barely responded to organic vapors.
|
|
pubmed:language |
eng
|
|
pubmed:journal |
|
|
pubmed:citationSubset |
IM
|
|
pubmed:chemical |
|
|
pubmed:status |
MEDLINE
|
|
pubmed:month |
Mar
|
|
pubmed:issn |
1520-510X
|
|
pubmed:author |
|
|
pubmed:issnType |
Electronic
|
|
pubmed:day |
21
|
|
pubmed:volume |
50
|
|
pubmed:owner |
NLM
|
|
pubmed:authorsComplete |
Y
|
|
pubmed:pagination |
2061-3
|
|
pubmed:meshHeading |
pubmed-meshheading:21338106-Adsorption,
pubmed-meshheading:21338106-Cobalt,
pubmed-meshheading:21338106-Crystallography, X-Ray,
pubmed-meshheading:21338106-Ions,
pubmed-meshheading:21338106-Lanthanoid Series Elements,
pubmed-meshheading:21338106-Models, Molecular,
pubmed-meshheading:21338106-Organometallic Compounds,
pubmed-meshheading:21338106-Particle Size,
pubmed-meshheading:21338106-Polymers,
pubmed-meshheading:21338106-Porosity,
pubmed-meshheading:21338106-Surface Properties
|
|
pubmed:year |
2011
|
|
pubmed:articleTitle |
Ln-Co-based rock-salt-type porous coordination polymers: vapor response controlled by changing the lanthanide ion.
|
|
pubmed:affiliation |
Division of Chemistry, Faculty of Science, Hokkaido University, North-10, West-8, Kita-Ku, Sapporo 060-0810, Japan. akoba@sci.hokudai.ac.jp
|
|
pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
|
