Source:http://linkedlifedata.com/resource/pubmed/id/21337078
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
1
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pubmed:dateCreated |
2011-2-21
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pubmed:abstractText |
In this work we investigate the influence of the adsorption of ions on the impedance spectroscopy of an electrolytic cell. We consider that the positive and negative ions present in a dielectric liquid are adsorbed in the electrode surfaces with different adsorption energies. This difference in adsorption energies causes an additional plateaux in the limit of the low-frequency range of the real part of the impedance Z. In the same frequency range, a second minimum in the imaginary part of Z is predicted. The theory is illustrated with measurements of the impedance of an electrolytic solution in the frequency range from 10(-2) Hz to 1 KHz. A comparison between the present model and others from the literature to describe the experimental results is also made.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical | |
pubmed:status |
MEDLINE
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pubmed:month |
Jan
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pubmed:issn |
1292-895X
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pubmed:author | |
pubmed:issnType |
Electronic
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pubmed:volume |
34
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
10
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pubmed:meshHeading |
pubmed-meshheading:21337078-Adsorption,
pubmed-meshheading:21337078-Dielectric Spectroscopy,
pubmed-meshheading:21337078-Electrodes,
pubmed-meshheading:21337078-Electrolysis,
pubmed-meshheading:21337078-Models, Theoretical,
pubmed-meshheading:21337078-Potassium Chloride,
pubmed-meshheading:21337078-Surface Properties
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pubmed:year |
2011
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pubmed:articleTitle |
The influence of adsorption phenomena on the impedance spectroscopy of an electrolytic cell.
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pubmed:affiliation |
Instituto de Física, Universidade de São Paulo, P.O. Box 66318, 05314-970, SP-Brazil. f_batalioto@yahoo.com.br
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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