Linked Life Data

21319238

Source:http://linkedlifedata.com/resource/pubmed/id/21319238

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
8
pubmed:dateCreated
2011-2-14
pubmed:abstractText
A family of linear Dy(3) and Tb(3) clusters have been facilely synthesized from the reactions of DyCl(3), the polydentate 3-methyloxysalicylaldoxime (MeOsaloxH(2) ) ligand with auxiliary monoanionic ligands, such as trichloroacetate, NO(3)(-), OH(-), and Cl(-). Complexes 1-5 contain a nearly linear Ln(3) core, with similar Ln···Ln distances (3.6901(4)-3.7304(3) Å for the Dy(3) species, and 3.7273(3)-3.7485(5) Å for the Tb(3) species) and Ln···Ln···Ln angles of 157.036(8)-159.026(15)° for the Dy(3) species and 157.156(8)-160.926(15)° for the Tb(3) species. All three Ln centers are bridged by the two doubly-deprotonated [MeOsalox](2-) ligands and two of the four [MeOsaloxH](-) ligands through the N,O-?(2)-oximato groups and the phenoxo oxygen atoms (Dy-O-Dy angles=102.28(16)-106.85(13)°; Tb-O-Tb angles=102.00(11)-106.62(11)°). The remaining two [MeOsaloxH](-) ligands each chelate an outer Ln(III) center through their phenoxo oxygen and oxime nitrogen atoms. Magnetic studies reveal that both Dy(3) and Tb(3) clusters exhibit significant ferromagnetic interactions and that the Dy(3) species behave as single-molecule magnets, expanding upon the recent reports of the pure 4f type SMMs.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Feb
pubmed:issn
1521-3765
pubmed:author
pubmed:copyrightInfo
Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
pubmed:issnType
Electronic
pubmed:day
18
pubmed:volume
17
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
2458-66
pubmed:meshHeading
pubmed:year
2011
pubmed:articleTitle
Pure trinuclear 4f single-molecule magnets: synthesis, structures, magnetism and ab initio investigation.
pubmed:affiliation
Key Laboratory of Synthetic Bioinorganic Chemistry of Ministry of Education, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, P. R. China.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't