Linked Life Data

21299209

Source:http://linkedlifedata.com/resource/pubmed/id/21299209

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
8
pubmed:dateCreated
2011-2-24
pubmed:abstractText
The 1-arsa-3-germaallene Tip(t-Bu)Ge?C?AsMes* (1, Tip = 2,4,6-triisopropylphenyl, Mes* = 2,4,6-tri-tert-butylphenyl), a stable heavier group 14 and 15 congener of allenes, has been synthesized by debromofluorination of Tip(t-Bu)Ge(F)-C(Br)?AsMes*. It reacts with methanol and 2,3-dimethyl-1,3-butadiene by the Ge?C double bond. The allenic-type structure of 1, featuring cumulated Ge?C and C?As double bonds, has been evidenced by means of spectroscopic and single-crystal X-ray determination. The electronic properties involved in this new system were obtained from DFT calculations. The mechanism of the reaction between 1 and the dimethylbutadiene is also described to understand the observed regio- and chemoselectivity.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Mar
pubmed:issn
1520-5126
pubmed:author
pubmed:issnType
Electronic
pubmed:day
2
pubmed:volume
133
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
2366-9
pubmed:meshHeading
pubmed:year
2011
pubmed:articleTitle
1-arsa-3-germaallene Tip(t-Bu)Ge?C?AsMes*: the heaviest mixed group 14 and 15 heteroallenic compound.
pubmed:affiliation
Universite? de Toulouse, UPS, LHFA, CNRS, UMR 5069, Toulouse, France.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't