21274470

Source:http://linkedlifedata.com/resource/pubmed/id/21274470

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0037093, umls-concept:C0040302, umls-concept:C0332282, umls-concept:C0443286, umls-concept:C0682951, umls-concept:C1879547
pubmed:issue	11
pubmed:dateCreated	2011-3-2
pubmed:abstractText	The Ti=NNMe(2) group of Cp*Ti{MeC(N(i)Pr)(2)}(NNMe(2)) undergoes 1,2-addition with Si-Cl and reversible addition with Si-H bonds of RSiH(2)X (R = Ph or Bu; X = Cl or H). Labeling studies show that the so-formed silylhydrazide-hydride products react with primary silanes or H(2)via ?-bond metathesis between Ti-H and either Si-H or H-H.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/9610838
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Mar
pubmed:issn	1364-548X
pubmed:author	pubmed-author:MountfordPhilipP, pubmed-author:NGE KEK, pubmed-author:NovaAinaraA, pubmed-author:TiongPei JenPJ
pubmed:issnType	Electronic
pubmed:day	21
pubmed:volume	47
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	3147-9
pubmed:year	2011
pubmed:articleTitle	Si-H and Si-Cl bond activation reactions of titanium hydrazides with silanes and subsequent Ti-H/E-H (E = Si or H) ?-bond metathesis.
pubmed:affiliation	Chemistry Research Laboratory, University of Oxford, Mansfield Road, Oxford OX1 3TA, UK.
pubmed:publicationType	Journal Article