Source:http://linkedlifedata.com/resource/pubmed/id/21267484
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
11
|
| pubmed:dateCreated |
2011-3-2
|
| pubmed:abstractText |
[K(2,2,2-crypt)](2)[As(7)]·THF, 1 (2,2,2-crypt = 4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane) is the first well characterized seven-atom radical anion of group 15. UV-Vis spectroscopy confirms the presence and electronic structure of [As(7)](2-). Cyclic voltammetry in DMF solution shows the As(7)(3-)/As(7)(2-) redox couple as a one-electron reversible process. Theoretical investigations explore the bonding and properties of compound 1.
|
| pubmed:language |
eng
|
| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:month |
Mar
|
| pubmed:issn |
1364-548X
|
| pubmed:author |
pubmed-author:KeXianglinX,
pubmed-author:KhannaShiv NSN,
pubmed-author:MandalSukhenduS,
pubmed-author:QianMeichunM,
pubmed-author:ReberArthur CAC,
pubmed-author:RenZ BZB,
pubmed-author:SaavedraHéctor MHM,
pubmed-author:SchifferPeterP,
pubmed-author:SenAyusmanA,
pubmed-author:SenSaikatS,
pubmed-author:WeissPaul SPS
|
| pubmed:issnType |
Electronic
|
| pubmed:day |
21
|
| pubmed:volume |
47
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
3126-8
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| pubmed:year |
2011
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| pubmed:articleTitle |
The Zintl ion [As7]2-: an example of an electron-deficient As(x) radical anion.
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| pubmed:affiliation |
Department of Chemistry, The Pennsylvania State University, University Park, PA 16802, USA.
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| pubmed:publicationType |
Journal Article
|