Source:http://linkedlifedata.com/resource/pubmed/id/21202580
Switch to
| Predicate | Object |
|---|---|
| rdf:type | |
| pubmed:issue |
Pt 6
|
| pubmed:dateCreated |
2011-1-4
|
| pubmed:abstractText |
The title compound, C(16)H(13)IO(2)S, was prepared by the oxidation of 2-(4-iodo-phen-yl)-5-methyl-3-methyl-sulfanyl-1-benzofuran with 3-chloro-peroxy-benzoic acid. The 4-iodo-phenyl ring makes a dihedral angle of 37.97?(9)° with the plane of the benzofuran fragment, and the O atom and the methyl group of the methyl-sulfinyl substituent lie on opposite sides of this plane. The mol-ecular packing is stabilized by C-H?? inter-actions between H atoms on the 4-iodo-phenyl ring and the benzofuran rings, and by an I?O halogen bond of 3.252?(2)?Å with a nearly linear C-I?O angle of 163.06?(8)°. In addition, the stacked mol-ecules exhibit inversion-related S?O contacts [3.209?(2)?Å] involving the sulfinyl groups.
|
| pubmed:commentsCorrections | |
| pubmed:language |
eng
|
| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:issn |
1600-5368
|
| pubmed:author | |
| pubmed:issnType |
Electronic
|
| pubmed:volume |
64
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
o1061
|
| pubmed:dateRevised |
2011-11-11
|
| pubmed:year |
2008
|
| pubmed:articleTitle |
2-(4-Iodo-phen-yl)-5-methyl-3-methyl-sulfinyl-1-benzofuran.
|
| pubmed:publicationType |
Journal Article
|