Linked Life Data

21201371

Source:http://linkedlifedata.com/resource/pubmed/id/21201371

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
Pt 2
pubmed:dateCreated
2011-1-4
pubmed:abstractText
The reaction of 1,4-bis-(4,5-dihydro-1H-imidazol-2-yl)benzene (bib) with silver(I) nitrate in a 1:1 molar ratio generates the metallacyclic title complex, [Ag(2)(C(12)H(14)N(4))(2)](NO(3))(2)·2H(2)O, in which the bib ligand displays a cis configuration. Each bib ligand acts as a bidentate bridging ligand connecting a pair of Ag(I) ions to form a [2 + 2] metallamacrocycle in which the Ag?Ag distance is 6.77?(2)?Å. Each Ag(I) ion has weak contacts (2.91?Å) with the nitrate anion. The uncoordinated water mol-ecules make hydrogen bonds with nitrate O atoms, forming chains. The H atoms attached to the uncoordinated nitro-gen inter-act with these chains through N-H?O hydrogen bonds, forming layers parallel to the (11) plane.
pubmed:commentsCorrections
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:issn
1600-5368
pubmed:author
pubmed:issnType
Electronic
pubmed:volume
64
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
m427-8
pubmed:dateRevised
2011-11-11
pubmed:year
2008
pubmed:articleTitle
Bis[?-1,4-bis-(4,5-dihydro-1H-imidazol-2-yl)benzene-?N:N]silver(I) dinitrate dihydrate.
pubmed:affiliation
School of Chemical and Material Engineering, Jiangnan University, 1800 Lihu Road, Wuxi, Jiangsu Province 214122, People's Republic of China.
pubmed:publicationType
Journal Article