Source:http://linkedlifedata.com/resource/pubmed/id/21200591
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
Pt 1
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| pubmed:dateCreated |
2011-1-4
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| pubmed:abstractText |
The title compound, [Cu(C(7)H(3)NO(5))(C(12)H(8)N(2))(H(2)O)]·4.5H(2)O or [Cu(hypydc)(phen)(H(2)O)]·4.5H(2)O (phen is 1,10-phenanthroline and hypydcH(2) is 4-hydroxy-pyridine-2,6-dicarboxylic acid), was obtained by the reaction of copper(II) nitrate hexa-hydrate with the proton-transfer compound (phenH)(2)(hypydc) in aqueous solution. Both the cationic and the anionic fragments of the proton-transfer compound are involved in complexation. Each Cu(II) atom has a distorted octa-hedral geometry. It is hexa-coordinated by three O atoms and three N atoms, from one phen fragment (as bidentate ligand), one (hypydc)(2-) unit (as tridentate ligand) and a water mol-ecule. In the crystal structure, O-H?O and C-H?O hydrogen bonds, and ?-? stacking inter-actions [centroid-to-centroid distance 3.5642?(11)?Å] between the phen ring systems, contribute to the formation of a three-dimensional supra-molecular structure.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:issn |
1600-5368
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| pubmed:author | |
| pubmed:issnType |
Electronic
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| pubmed:volume |
64
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
m252-3
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| pubmed:dateRevised |
2011-11-11
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| pubmed:year |
2007
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| pubmed:articleTitle |
Aqua-(4-hydroxy-pyridine-2,6-dicarboxyl-ato)(1,10-phenanothroline)copper(II) 4.5-hydrate.
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| pubmed:publicationType |
Journal Article
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