Source:http://linkedlifedata.com/resource/pubmed/id/21174403
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
4
|
| pubmed:dateCreated |
2011-2-18
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| pubmed:abstractText |
The Merrifield solid-phase peptide synthesis technique has been adapted to the synthesis of homo- and heterometallic metal?organic complex arrays (MOCAs). A terpyridine-appended and Fmoc-protected L-tyrosine derivative was metalated with Pt(II), Rh(III), or Ru(II) ions in solution and sequentially coupled at the surface of functionalized polymeric resin to give a metal complex triad (Rh?Pt?Ru), tetrad (Ru?Rh?Pt?Pt), pentad (Rh?Pt?Ru?Pt?Rh), and hexad (Rh?Pt?Ru?Pt?Rh?Pt) with specific metal sequence arrangements. These were cleaved from the resin, and their character was confirmed by mass spectrometry.
|
| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:month |
Feb
|
| pubmed:issn |
1520-5126
|
| pubmed:author | |
| pubmed:issnType |
Electronic
|
| pubmed:day |
2
|
| pubmed:volume |
133
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| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
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| pubmed:pagination |
759-61
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| pubmed:year |
2011
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| pubmed:articleTitle |
Synthesis of metal?organic complex arrays.
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| pubmed:affiliation |
International Center for Materials Nanoarchitectonics, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan.
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| pubmed:publicationType |
Journal Article
|