Source:http://linkedlifedata.com/resource/pubmed/id/21052603
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
15
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| pubmed:dateCreated |
2011-3-31
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| pubmed:abstractText |
Compared to earlier single site catalysts, greatly enhanced rates of electrocatalytic water oxidation by the Ru carbene catalyst [Ru(tpy)(Mebim-py)(OH(2))](2+) (tpy = 2,2':6',2''-terpyridine; Mebim-py = 3-methyl-1-pyridylbenzimidazol-2-ylidene) have been observed. The mechanism appears to be the same with proton coupled electron transfer (PCET) activation to Ru(V)=O(3+) followed by O-O coupling and further oxidation. An important factor in the enhanced reactivity of the carbene complex may come from increased driving force for the O-O bond forming step.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Apr
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| pubmed:issn |
1477-9234
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| pubmed:author | |
| pubmed:issnType |
Electronic
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| pubmed:day |
21
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| pubmed:volume |
40
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| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
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| pubmed:pagination |
3789-92
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| pubmed:year |
2011
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| pubmed:articleTitle |
Rapid catalytic water oxidation by a single site, Ru carbene catalyst.
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| pubmed:affiliation |
Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, NC 27599, USA.
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| pubmed:publicationType |
Journal Article
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