Source:http://linkedlifedata.com/resource/pubmed/id/21043523
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
23
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pubmed:dateCreated |
2010-11-29
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pubmed:abstractText |
A newly synthesized azine-based receptor (L) is found to show remarkable specificity toward the Hg(2+) ion in aqueous media over other metal ions. Coordination of L to Hg(2+) induces a detectable change in color and a turn-on fluorescence response. Restricted C=N isomerization of the azine moieties in the excited state as well as the Photoinduced Electron Transfer (PET) involving the lone pair of electrons of N(1)/N(2) on coordination of L to the Hg(2+) ion account for the turn-on fluorescence response. This reagent could be used for imaging the accumulation of Hg(2+) ions in Epithelial cell line KB 31 cells.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical | |
pubmed:status |
MEDLINE
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pubmed:month |
Dec
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pubmed:issn |
1523-7052
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pubmed:author | |
pubmed:issnType |
Electronic
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pubmed:day |
3
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pubmed:volume |
12
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
5406-9
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pubmed:meshHeading |
pubmed-meshheading:21043523-Azides,
pubmed-meshheading:21043523-Cations, Divalent,
pubmed-meshheading:21043523-Cell Line,
pubmed-meshheading:21043523-Cell Survival,
pubmed-meshheading:21043523-Crystallography, X-Ray,
pubmed-meshheading:21043523-Humans,
pubmed-meshheading:21043523-Isomerism,
pubmed-meshheading:21043523-Mercury,
pubmed-meshheading:21043523-Molecular Structure
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pubmed:year |
2010
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pubmed:articleTitle |
Azine-based receptor for recognition of Hg2+ ion: crystallographic evidence and imaging application in live cells.
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pubmed:affiliation |
Central Salt and Marine Chemicals Research Institute (CSIR), Bhavnagar 364002, Gujarat, India.
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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