Linked Life Data

20939525

Source:http://linkedlifedata.com/resource/pubmed/id/20939525

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
21
pubmed:dateCreated
2010-10-29
pubmed:abstractText
An approach to resorcylic acid lactones is described, exploiting an intramolecular olefination reaction for the generation of the 14-membered macrolactone. The synthetic route gave zearalenone precursors, and the preparations of other RAL analogues, trans- and cis-resorcylides are included, the latter being prepared by photoisomerization of the trans-isomer. ?-Haloketone derivatives were also prepared in a highly stereoselective manner by conjugate addition of chloride or bromide to the E-enone using boron trichloride and boron tribromide, respectively.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Nov
pubmed:issn
1520-6904
pubmed:author
pubmed:issnType
Electronic
pubmed:day
5
pubmed:volume
75
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
7404-7
pubmed:meshHeading
pubmed:year
2010
pubmed:articleTitle
Access to resorcylic acid lactones via phosphonate based intramolecular olefination.
pubmed:affiliation
School of Chemistry, National University of Ireland, Galway, University Road, Galway, Ireland.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't