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rdf:type |
|
|
lifeskim:mentions |
|
|
pubmed:issue |
21
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|
pubmed:dateCreated |
2010-10-29
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pubmed:abstractText |
Sterically demanding and conformationally stable N,N'-ditertiaryalkyl-N,N'-diphenyl acyclic diaminocarbenes (ADCs) were developed. Bulky ADC-Au catalysts not only showed competitive reactivities in hydroamination and enyne cyclization but also demonstrated unique ligand properties different from bulky N-heterocyclic carbene (NHC) counterparts.
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pubmed:language |
eng
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pubmed:journal |
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pubmed:citationSubset |
IM
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pubmed:chemical |
|
|
pubmed:status |
MEDLINE
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pubmed:month |
Nov
|
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pubmed:issn |
1523-7052
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pubmed:author |
|
|
pubmed:issnType |
Electronic
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pubmed:day |
5
|
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pubmed:volume |
12
|
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pubmed:owner |
NLM
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|
pubmed:authorsComplete |
Y
|
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pubmed:pagination |
4860-3
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pubmed:meshHeading |
|
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pubmed:year |
2010
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|
pubmed:articleTitle |
Novel acyclic diaminocarbene ligands with increased steric demand and their application in gold catalysis.
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|
pubmed:affiliation |
Department of Chemistry, University of Florida, P.O. Box 117200, Gainesville, Florida 32611-7200, United States.
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|
pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
|
