Linked Life Data

2089414

Source:http://linkedlifedata.com/resource/pubmed/id/2089414

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
4
pubmed:dateCreated
1991-5-28
pubmed:abstractText
The triplet energy of alpha-terthienyl has been determined by heavy atom-induced optical absorption: the value of 39.7 +/- 1.5 kcal/mol is consistent with earlier energy transfer work. Combining this result with calorimetric data from optoacoustic calorimetry indicates that intersystem crossing occurs with at least 90% efficiency in polar and non-polar solvents. The quantum yields for singlet oxygen formation via energy transfer from triplet alpha-terthienyl have been obtained from time-resolved measurements of its IR phosphorescence: these yields are in the 0.6-0.8 range in non-polar and polar (hydroxylic and non-hydroxylic) solvents.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Oct
pubmed:issn
0031-8655
pubmed:author
pubmed:issnType
Print
pubmed:volume
52
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
655-9
pubmed:dateRevised
2006-11-15
pubmed:meshHeading
pubmed:year
1990
pubmed:articleTitle
Efficiency of the photoprocesses leading to singlet oxygen (1 delta g) generation by alpha-terthienyl: optical absorption, optoacoustic calorimetry and infrared luminescence studies.
pubmed:affiliation
Division of Chemistry, National Research Council of Canada, Ottawa.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't