Linked Life Data

20880540

Source:http://linkedlifedata.com/resource/pubmed/id/20880540

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
2
pubmed:dateCreated
2010-10-18
pubmed:abstractText
The decomposition reaction of the purple dye murexide in acidic media is used as a probe indicator for protons in nonionic microemulsions. The reaction kinetics primarily rely on the proton concentration and permit assessment of the proton activity in the nonionic microemulsions of water/cyclohexane/Igepal and water/heptane/Igepal. The experiments performed in the two microemulsions covered a wide range of water-to-oil mass fraction for the two systems. The kinetic runs were monitored under pseudo-first order conditions by the stopped-flow technique. The equilibrium constants for the formation of purpuric acid and the kinetic constants for the ensuing decomposition reaction fulfill a trend consistent with the micro compartmentalized nature of the multicomponent medium, and support the use of murexide as an indicator of the proton activity in microemulsions.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Dec
pubmed:issn
1095-7103
pubmed:author
pubmed:copyrightInfo
Copyright © 2010 Elsevier Inc. All rights reserved.
pubmed:issnType
Electronic
pubmed:day
15
pubmed:volume
352
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
465-9
pubmed:meshHeading
pubmed:year
2010
pubmed:articleTitle
Evaluation of proton activity in microemulsions by a kinetic probe.
pubmed:affiliation
Universidad de Burgos, Departamento de Química, 09001 Burgos, Spain.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't