Source:http://linkedlifedata.com/resource/pubmed/id/20856989
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
41
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| pubmed:dateCreated |
2010-10-13
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| pubmed:abstractText |
A reaction of FeCl(2) with tris(2-pyridylthio)methane (tptmH) produced the carbanion complex [Fe(tptm)(CH(3)CN)(2)](FeCl(4)){(C(2)H(5))(3)NH}. When FeI(2) was used instead of FeCl(2), the carbene complex [FeI(pyt)(bptmd)] (pyt = 2-pyridinethiolate, bptmd = bis(2-pyridylthio)methylidene) was isolated. The carbene forms [FeX(pyt)(bptmd)](n+) (n = 1 for X = CH(3)CN, n = 0 for X = I) were observed for [Fe(tptm)(CH(3)CN)(2)](FeCl(4)){(C(2)H(5))(3)NH} and [FeI(pyt)(bptmd)] in chloroform, whereas the carbene-carbanion equilibrium was observed in acetonitrile by NMR measurements. The thermodynamic parameters were evaluated by variable temperature (1)H NMR measurements using the diamagnetic salt [Fe(tptm)(CH(3)CN)(2)]PF(6) for [Fe(tptm)(CH(3)CN)(2)](+)? [Fe(pyt)(bptmd)(CH(3)CN)](+) + CH(3)CN (?H = 23 kJ mol(-1), ?S = 55 J mol(-1) K(-1)).
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Nov
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| pubmed:issn |
1477-9234
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| pubmed:author | |
| pubmed:issnType |
Electronic
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| pubmed:day |
7
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| pubmed:volume |
39
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
9988-93
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| pubmed:year |
2010
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| pubmed:articleTitle |
Carbene-carbanion equilibrium for tris(2-pyridylthio)methanido Fe(II) complexes.
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| pubmed:affiliation |
Department of Material Science, Graduate School of Science, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka, 558-8585, Japan.
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| pubmed:publicationType |
Journal Article
|